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Electrochemical Determination of the Superoxide Ion Concentration from KO2 Dissolved in Dimethyl Sulfoxide

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Abstract

An electrochemical determination of the O2 concentration from KO2 in DMSO solution using steady state microelectrode voltammetry shows that the KO2/DMSO method with the combined use of a crown compound or sonication is a reliable and simple technique for introduction of O2 to the biomimitic reaction system.

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References

  1. J. S. Valentine and A. B. Curtis, J. Am. Chem. Soc., 1975, 9, 224.

    Article  Google Scholar 

  2. C. J. Pederson, J. Am. Chem. Soc., 1967, 89, 7017.

    Article  Google Scholar 

  3. C. L. Liotta and H. P. Harris, J. Am. Chem. Soc., 1974, 96, 2250.

    Article  CAS  Google Scholar 

  4. M. Tsushima, K. Tokuda, and T. Ohsaka, Anal. Chem., 1994, 66, 4551.

    Article  CAS  Google Scholar 

  5. T. Ohsaka, M. Tsushima, T. Okajima, and K. Tokuda, Denki Kagaku, 1994, 62, 1300.

    Article  CAS  Google Scholar 

  6. J. A. Fee and P. G. Hildenbrand, FEBS Lett., 1974, 39, 79.

    Article  CAS  Google Scholar 

  7. T. Ozawa, A. Hanaki, and H. Yamamoto, FEBS Lett., 1977, 74, 99.

    Article  CAS  Google Scholar 

  8. S. Kim, R. DiCosimo, and S. S. Filippo, Jr., Anal. Chem., 1979, 51, 67.

    Google Scholar 

  9. R. L. Arudi, A. O. Allen, and B. H. J. Bielski, FEBS Lett., 1981, 135, 265.

    Article  CAS  Google Scholar 

  10. H. Gampp and S. J. Lippard, Inorg. Chem., 1983, 22, 357.

    Article  CAS  Google Scholar 

  11. T. Oritani, N. Fukuhara, T. Okajima, F. Kitamura, and T. Ohsaka, Inorg. Chim. Acta, 2004, 357, 436.

    Article  CAS  Google Scholar 

  12. Y. Kirino and T. Ozawa, “Essence ESR”, 1993, Hirokawa Publishing, Tokyo, 91.

    Google Scholar 

  13. J. R. Harbour, V. Chow, and J. R. Bolton, Can. J. Chem., 1974, 52, 3549.

    Article  CAS  Google Scholar 

  14. Y.-H. Kim, S.-C. Lim, M. Hoshino, Y. Ohtsuka, and T. Ohishi, Chem. Lett., 1989, 167.

    Google Scholar 

  15. A. A. Frimer, “Oxygen Radicacl in Biology and Medicine”, 1988, Plenum Press, New York, 29.

    Book  Google Scholar 

  16. Y. Saito, Rev. Porlaogr., 1968, 6, 177.

    Google Scholar 

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Kishioka, Sy., Takekawa, T. & Yamada, A. Electrochemical Determination of the Superoxide Ion Concentration from KO2 Dissolved in Dimethyl Sulfoxide. ANAL. SCI. 20, 1465–1466 (2004). https://doi.org/10.2116/analsci.20.1465

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  • DOI: https://doi.org/10.2116/analsci.20.1465

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